Photochemical fabrication of molecular devices
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概要
- 論文の詳細を見る
We present a novel way to fabricate electronic devices from a molecular charge transfer salt Ag(DM)2 by simple illumination, which realizes a junction-structure in the single molecular crystal. The electrical conductivity of the selected parts of samples can be controlled by illimination time and power. The electrical behavior gradually turned semiconducting from metallic one by illumination. X-ray photoelectron spectroscopy, Raman spectroscopy and X-ray absorption fine structure indicated that illumination should transfer some electrons from the conducting DM columns to the Ag ions. The X-ray powder diffraction pattern indicated that original crystal lattice was maintained after the illumination. These observations imply that the illumination practically effected doping (or rather dedoping) on the material.
- Elsevier B.V.の論文
- 2006-07-15
著者
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Asakura Kiyotaka
Catalyst Research Center Hokkaido University
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Asakura K
Center Of Spectrochemistry Graduate School Of Science The University Of Tokyo
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Asakura Kiyotaka
Catalysis Res. Center Hokkaido Univ. Kita 21-10 Kita-ku Sapporo 001-0021 Jpn
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Asakura K
Catalysis Research Center Hokkaido University
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Asakura K
Hokkaido Univ. Sapporo Jpn
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Asakura K
Department Of Quantum Science And Engineering Graduate School Of Engineering Hokkaido University
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Asakura Kiyotaka
Center Of Spectrochemistry Graduate School Of Science The University Of Tokyo
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Naito Toshio
Division Of Chemistry Graduate School Of Science Hokkaido University
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Naito Toshio
Division Of Chemistry Faculty Of Science Hokkaido University
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INABE Tamotsu
Department of Chemistry, Graduate School of Science, Hokkaido University
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Inabe Tamotsu
Division Of Chemistry Graduate School Of Science Hokkaido University
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SUGAWARA Hideyuki
Division of Chemistry, Graduate School of Science, Hokkaido University
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NIIMI Hironobu
Catalysis Research Center, Hokkaido University
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Miyamoto Takeshi
Department Of Quantum Science And Engineering Graduate School Of Engineering Hokkaido University
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