Effects of water on reactions for waste treatment, organic synthesis, and bio-refinery in sub- and supercritical water

スポンサーリンク

概要

• 論文の詳細を見る

• Current research analyzing the effects of water in the field of homogeneous and heterogeneous reactions of organics in sub- and supercritical water are reviewed in this article. Since the physical properties of water (e.g., density, ion product and dielectric constants) can affect the reaction rates and mechanisms of various reactions, understanding the effects that water can have is important in controlling reactions. For homogeneous reactions, the effects of water on oxidation, hydrolysis, aldol condensation, Beckman rearrangement and biomass refining were introduced including recent experimental results up to 100 MPa using special pressure-resistance equipment. For heterogeneous reactions, the effects of ion product on acid/base-catalyzed reactions, such as hydrothermal conversion of biomass-related compounds, organic synthesis in the context of bio-refinery, and hydration of olefins were described and how the reaction paths are controlled by the concentration of water and hydrogen ions was summarized.

• 公益社団法人日本生物工学会の論文

著者

• Akizuki Makoto

  Department Of Applied Chemistry Faculty Of Engineering Okayama University

• Oshima Yoshito

  Department Of Chemical Engineering Facutly Of Engineering The University Of Tokyo

• Hayashi Rumiko

  Division For Environment Health And Safety The University Of Tokyo

• Fujii Tatsuya

  Research Center for Compact Chemical System, National Institute of Advanced Industrial Science and Technology

関連論文

• Degradation of Soy Sauce Cake by Subcritical Water Treatment
• A NOVEL LASER-INDUCED SYNTHESIS OF 1, 1-DICHLOROETHYLENE FROM 1, 1-DICHLOROETHANE
• The Ring-Opening Reaction of 3, 3, 3-Trifluoropropene Oxide with Carbanions : Reaction of α-Cyanocarbanions
• Aerobic Oxidation of Cyclohexane Catalyzed by Fe(III)(5, 10, 15, 20-tetrakis(pentafluorophenyl)porphyrin)Cl in Sub- and Super-Critical Co_2
• Hydrogenation of Acetone in Supercritical Water Using Formic Acid : Rapid Hydrogenation Observed at a Long Retention Time
• Contribution of Ionic Reactions to Sub- and Supercritical Water Oxidation of Phenol
• PFR and CSTR Analyses of Supercritical Water Oxidation of Methanol
• Kinetics and Mechanisms of Supercritical Water Oxidation of Methylamines
• Degradation of Soy Sauce Cake by Subcritical Water Treatment
• Effects of water on reactions for waste treatment, organic synthesis, and bio-refinery in sub- and supercritical water

スポンサーリンク