A11 多官能アリル架橋重合における高架橋密度ネットワークポリマー前駆体からなるゲルの超音波照射分解(口頭発表)

概要

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In free-radical multiallyl crosslinking polymerization accompanied by degradative monomer chain transfer characteristic of allyl polymerization, the structure of network polymer precursor (NPP) obtained just before gelation would become core-shell type dendritic or nanogel-like. The network polymer would consist of NPPs with high crosslink density; the resulting gel may be facile to be degradable through fragile crosslink units between nanogel-like NPPs. The present work deals with the microwave-irradiated degradation of gels consisting of NPPs with high crosslink density, considering the characteristics of network polymer as crosslinked system material consisting of NPP modules.
日本ソノケミストリー学会の論文
2008-12-05