2b04 側鎖にオリゴシロキサン鎖を有するペリレンテトラカルボン酸ビスイミド誘導体のカラムナー相での高速電子輸送(分子配向エレクトロニクス,口頭発表,2012年日本液晶学会討論会)
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概要
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Liquid crystalline perylene tetracarboxylic bisimide derivative 1 bearing four disiloxane chains was synthesized. Compound 1 exhibits a hexagonal ordered columnar phase at room temperature. In the columnar phase, disiloxane chains interdigitate to stabilize the columnar structure. In the columns, molecules are closely stacked. The time-of-flight measurement reveals a high electron mobility exceeding 0.1 cm^2/Vs in the columnar phase at room temperature. Compound 1 is soluble in various organic solvents and LC thin films can be produced by a spin-coating method. In particular, uniaxially aligned LC thin films can be formed on friction-transferred substrates.
- 2012-08-20
著者
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Sonoda Akinari
Health Research Institute National Institute Of Advanced Industrial Science And Technology (aist)
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苑田 晃成
産総研健康
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舟橋 正浩
香川大工
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