ペルフルオロイソプロペニル基を有するアリル化合物の重合

概要

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The investigation on the radical polymerization reactivity of allyl compounds bearing perfluoroisopropenyl group [CH_2=CH-(CH_2)_n-COOC(CF_3)=CF_2 (n=3, 4, 7, and 8)] was carried out since allyl polymerization of 4-pentenoyloxypentafluoropropene (n=2) successfully produced high molecular weight polymers bearing 1.8×10^4 as the highest molecular weight under moderate radical polymerization condition. A polymer possessing 9.6×10^3 as the highest molecular weight was obtained from radical polymerization of 5-hexenoyloxy-pentafluoropropene (n=3). The polymer possesses perfluoroisopropenyl groups in side chains to yield adducts with tetrahydrofuran.
埼玉工業大学の論文