Charge-Transfer Dynamics in Cyano-Bridged M_A-Fe System(M_A=Mn, Fe, and Co)(Condensed matter: electronic structure and electrical, magnetic, and optical properties)
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概要
- 論文の詳細を見る
Charge-transfer (CT) dynamics has been investigated for Prussian blue-type M_A-Fe cyanides (M_A=Mn, Fe, and Co) grown in hydrophilic cavities of a Nafion 117 film. In all the compounds, we observed the suppression of the original CT absorption between neighboring transition metals. We found that the spectral profile of the slow component for the Fe compound is similar to that for the Co compound, reflecting the photo created d^6 state at the M_A site.
- 社団法人日本物理学会の論文
- 2008-09-15
著者
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Kamioka Hayato
Department Of Physics University Of Tsukuba
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MORITOMO Yutaka
Department of Physics, University of Tsukuba
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Moritomo Yutaka
Department Of Physics University Of Tsukuba
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Moritomo Yutaka
Department Of Applied Physics Nagoya University
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KOSAKA Wataru
Department of Chemistry, University of Tokyo
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OHKOSHI Shinichi
Department of Chemistry, University of Tokyo
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Kosaka Wataru
Department Of Chemistry School Of Science The University Of Tokyo
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Kosaka Wataru
Department Of Chemistry University Of Tokyo
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KAMIOKA Hayato
JASRI/SPring-8
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Ohkoshi Shinichi
Department Of Chemistry University Of Tokyo
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Ohkoshi Shinichi
Department Of Applied Chemistry School Of Engineering The University Of Tokyo:presto Jst
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Kosaka Wataru
Department Of Chemistry Division Of Material Sciences Graduate School Of Natural Science And Technology Kanazawa University
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Kamioka Hayato
Graduate School of Pure and Applied Science, University of Tsukuba
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