Structural Transition Induced by Charge-Transfer in RbMn[Fe(CN)_6] : Investigation by Synchrotron-Radiation X-ray Powder Analysis

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概要

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• Temperature dependence of atomic coordinates is determined for RbMn[Fe(CN)_6] by means of synchrotron-radiation (SR) X-ray powder structural analysis. We observed a structural transition from the cubic (F43m; Z=4) to the tetragonal (I4^^-m2; Z=2) phase at ≈210 K in the cooling run and at ≈300 K in the warming run. In the low-temperature tetragonal phase, we found Jahn-Tellar type distortion of the MnN_6 octahedra and compression of the averaged Fe-C bond distance. These structural data suggest that the structural transition is triggered by the inter-metallic charge-transfer from the Mn(II) site to the Fe(III) site.

• 社団法人日本物理学会の論文
• 2002-09-15

著者

• Kindo K

  Advanced Science Research Center Japan Atomic Energy Agency

• TAKATA Masaki

  Department of Applied Physics, Nagoya University

• SAKATA Makoto

  Department of Applied Physics, Nagoya University

• Takata M

  Department Of Physics Division Of Material Science Nagoya University

• KATO Kenichi

  Japan Synchrotron Radiation Research Institute, Spring-8

• Hiraoka T

  Faculty Of Integrated Arts And Science Hiroshima University

• MORITOMO Yutaka

  Department of Physics, University of Tsukuba

• Kosuge Koji

  Department Of Chemistry Graduate School Of Science Kyoto University

• Takata Masaki

  Department Of Applied Physics School Of Engineering Nagoya University

• Sakata M

  Kyorin Univ. Tokyo Jpn

• Sakata Makoto

  Department Of Applied Physics Faculty Of Engineering Nagoya University

• HASHIMOTO Kazuhito

  Research Center for Advanced Science and Technology, The University of Tokyo

• KURIKI Akira

  Department of Crystalline Materials Science, Nagoya University

• Moritomo Yutaka

  Department Of Applied Physics Nagoya University

• Hiraoka T

  Faculty Of Science And Engineering Saga University

• Hashimoto K

  The Institute Of Physical And Chemical Research (riken):graduate School Of Science And Engineering S

• TOKORO Hiroko

  Research Center for Advanced Science and Technology, University of Tokyo

• OHKOSHI Shin-ichi

  Research Center for Advanced Science and Technology, University of Tokyo

• Kuriki Akira

  Department Of Crystalline Materials Science Nagoya University

• Hashimoto K

  Department Of Applied Chemistry School Of Engineering The University Of Tokyo

• Tokoro Hiroko

  Department Of Chemistry School Of Science The University Of Tokyo

• Ohkoshi S

  Department Of Chemistry School Of Science The University Of Tokyo

• Ohkoshi Shin-ichi

  Research Center For Advanced Science And Technology The University Of Tokyo

• Kato Kenichi

  Japan Synchrotron Radiation Research Institute

• Hashimoto Kazuhito

  Research Center For Advanced Science And Technology The University Of Tokyo

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