SPECTROSCOPIC STUDIES OF HYBRID THIN FILMS CONSISTING OF A CLAY AND TETRATHIAFULVALENE

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概要

• 論文の詳細を見る

• We fabricated novel hybrid films consisting of a clay and cationic tetrathiafulvalene (TTF). The average distance between the TTF molecules adsorbed onto the clay sheet was controlled by changing the fabricating condition. The obtained films showed the absorption bands at around 450, 750 and 2000 nm, which were assigned to an intramolecular transition of TTF^+, and intermolecular transitions between TTF^+s and between TTF^+ and TTF^0, respectively. The relative absorbances of the bands were found to vary depending on the average distance between the TTF molecules adsorbed onto the clay sheet. This fact indicates that the electronic properties of the TTF molecules in the present films can be controlled by changing the fabricating condition.

• 日本粘土学会の論文

著者

• KAWAMATA JUN

  Department of Chemistry, Faculty of Science, Yamaguchi University

• Saito Gunzi

  Division Of Chemistry Graduate School Of Science Kyoto University

• Saito Gunzi

  Division Of Chemistry Graduate School Of Science Kyoto University:research Center For Low Temperatur

• Kawamata Jun

  Department Of Chemistry And Earth Sciences Faculty Of Science Yamaguchi University

• YOSHIDA Yukihiro

  Division of Chemistry, Graduate School of Science, Kyoto University

• Yoshida Yukihiro

  Division Of Chemistry Graduate School Of Science Kyoto University

• Suzuki Yasutaka

  Department Of Chemistry Faculty Of Science Yamaguchi University

• Kai Kazuya

  Division Of Chemistry Graduate School Of Science Kyoto University

• SEIKE RYUICHI

  Department of Chemistry, Faculty of Science, Yamaguchi University

• OKAWAHARA NOZOMI

  Department of Chemistry, Faculty of Science, Yamaguchi University

• FURUKAWA YU

  Department of Chemistry, Faculty of Science, Yamaguchi University

• Furukawa Yu

  Department Of Chemistry Faculty Of Science Yamaguchi University

• Seike Ryuichi

  Department Of Chemistry Faculty Of Science Yamaguchi University

• Okawahara Nozomi

  Department Of Chemistry Faculty Of Science Yamaguchi University

• Suzuki Yasutaka

  Department of Applied Chemistry, Faculty of Engineering, Saitama University

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