Description of Multipole in f-Electron Systems(Condensed matter: electronic structure and electrical, magnetic, and optical properties)
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概要
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A systematic description of multipole degrees of freedom is discussed on the basis of the Stevens' operator-equivalent technique. The generalized Stevens' multiplicative factors are derived for all of the electric and the magnetic multipoles relevant to f-electron systems. With extensive use of the Stevens' factors, we express the spatial dependences of the electric and the magnetic fields, and the electric and the magnetic charge densities of localized f electrons. The latter is utilized to draw wave functions including their magnetic profile in addition to their shape with the charge density. The definite relation between the operators as quantum-mechanical variables in a multipole exchange model and the multipole moments in expansion of electromagnetic fields is given. The general treatments for the exchange model with the random-phase-approximation (RPA) susceptibility and the Ginzburg-Landau free-energy expansion are discussed, using Ce_xLa_<1-x>B_6 as a typical example. The representative formula of the vector spherical harmonics are summarized, which are suitable basis for vector fields in the spherical expansion.
- 社団法人日本物理学会の論文
- 2008-06-15
著者
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Kusunose Hiroaki
Department Of Physics Ehime University
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Kusunose Hiroaki
Department Of Material Physics Faculty Of Engineering Science Osaka University
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