Mechanistic Study of Electrochemical Oxidation of 2,5-Dihydroxybenzoic Acid and 3,4-Dihydroxybenzaldehyde in the Presence of 3-Hydroxy-1H-phenalene-1-one
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概要
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The mechanism of the electrochemical oxidation of 2,5-dihydroxybenzoic acid and 3,4-dihydroxybenzaldehyde in the presence of 3-hydroxy-1H-phenaIene-1-one as a nucleophile has been studied in water/acetonitrile (80/20 v/v) solution using cyclic voltammetry and controlled-potential coulometry methods. The results indicate that the quinones derived from oxidation of 2,5-dihydroxybenzoic acid and 3,4-dihydroxybenzaldehyde participate in Michael addition reactions with 3-hydroxy-1H-phenalene-1-one and via ECE and ECEC mechanisms convert to the different products, with good yield under controlled potential conditions, at carbon electrode.
- 公益社団法人日本薬学会の論文
- 2008-04-01
著者
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Amani Amaneh
Faculty Of Chemistry Bu-ali-sina University
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NEMATOLLAHI Davood
Faculty of Chemistry, Bu-Ali Sina University
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Nematollahi Davood
Faculty Of Chemistry Bu-ali Sina University
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Nematollahi Davood
Faculty Of Chemistry Bu-ali-sina University
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