水に極めて難溶なモノマーを含むシード乳化共重合反応に及ぼす撹拌の影響

概要

論文の詳細を見る
Effect of agitation on the rate of batch seeded emulsion copolymerization of styrene and dodecyl methacrylate is studied. In the conditions studied, increase in agitation rate did not affect the rate of polymerization of styrene, but increased the rate of polymerization of dodecyl methacrylate. This suggests that diffusion of sparingly water-soluble monomer, whose water-solubility is less than that of dodecyl methacrylate, from monomer droplets to the aqueous phase is ratedetermining step in emulsion copolymerization system including sparingly water-soluble monomer.
福井大学の論文
2007-03-30