Relaxor Behaviors in Ferroelectric-Antiferroelectric Mixed Crystals
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概要
- 論文の詳細を見る
In order to search for relaxor ferroelectrics or relaxor antiferroelectrics in Pb-excluded substances, ferroelectric and antiferroelectric mixed crystals Rb_<1-x>(NH_4)_xH_2PO_4 are investigated from the theoretical viewpoint of the precursor to glass state. Both boundary regions between ferroelectric (FE) and glassy (G) phases, and between antiferroelectric (AFE) and glassy (G) phases are examined and relaxor-like behaviors are found in the present theory on X-ray diffraction and on dielectric constants. The relaxor-like behavior as an embryo of the glass is proposed in the antiferroelectric-glass (AFE-G) phase boundary region where the growth of glass ordering is shown in quite a different pattern from that of the FE-G phase boundary region. The condition for appearance of the relaxor is discussed as being due to the proton spatial correlation in structurally frustrated systems.
- 社団法人応用物理学会の論文
- 2002-11-30
著者
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Takahashi Kazuyoshi
Faculty Of Engineering Gifu University
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MATSUSHITA Eiko
Faculty of Engineering, Gifu University
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Matsushita Eiko
Faculty Of Engineering Gifu University
関連論文
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