Curie-point Pyrolysis of Cellulose in the Presence of Potassium Malate(Food & Nutrition)

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概要

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• Finely powdered cellulose was pyrolysed in a Curie-point pyrolyser, which was directly attached to a gas chromatograph and mass spectrometer (CPP-GC/MS), at 358℃ for 5 sec in He (gas) without any additives. The pyrolysis products were levoglucosenonc as the main component, 2-furaldehyde, 1,4:3,6-dianhydro-x-D-glucopyranose and 5-hydroxymethyl-2-furaldehyde. However, CPP-GC/MS of cellulose in the presence of potassium malate (5 % as potassium) gave 2-furanmethanol as the main component, and a number of low molecular compounds were formed; e.g., lactones, ketones and furans. A possible new reaction path for cellulose to 2-furanmethanol via D-xylulose is presented.

• 社団法人日本農芸化学会の論文
• 1990-04-23

著者

• Izawa Kazuo

  Tobacco Science Research Laboratory Japan Tobacco Inc.

• MATSUKURA Masao

  Tobacco Science Research Laboratory, Japan Tobacco Inc.

• ISHIZU Yoshiaki

  Tobacco Science Research Laboratory, Japan Tobacco Inc.

• Matsukura Masao

  Tobacco Science Research Laboratory Japan Tobacco Inc.

• Ishizu Yoshiaki

  Tobacco Science Research Laboratory Japan Tobacco Inc.

関連論文

• Curie-point Pyrolysis of Cellulose in the Presence of Potassium Malate(Food & Nutrition)

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