Reactions of Sodium Borohydride. IV. Reduction of Aromatic Sulfonyl Chlorides with Sodium Borohydride(Organic,Chemical)
スポンサーリンク
概要
- 論文の詳細を見る
Aromatic sulfonyl chlorides were reduced with sodium borohydride in tetrahydrofuran at 0℃ to the corresponding sulfinic acids in good yields. Further reduction proceeded when the reaction was carried out under reflux in tetrahydrofuran to give disulfide and thiophenol derivatives via sulfinic acid. Furthermore, sulfonamides were reduced with sodium borohydride by heating directly to give sulfide, disulfide and thiophenol derivatives, and diphenyl sulfone was reduced under similar conditions to give thiophenol and biphenyl.
- 公益社団法人日本薬学会の論文
- 1987-05-25
著者
-
Nose A
Daiichi Coll. Pharmaceutical Sciences Fukuoka Jpn
-
工藤 忠宏
Daiichi College of Pharmaceutical Sciences
-
NOSE ATSUKO
Daiichi College of Pharmaceutical Sciences
関連論文
- NOVEL AND FACILE REDUCTION OF HETEROCYCLIC COMPOUNDS WITH LANTHANOID METAL-HYDROCHLORIC ACID SYSTEM
- NOVEL REDUCTION OF CARBOXYLIC ACID, ESTER, AMIDE AND NITRILE WITH SAMARIUM OR YTTERIBIUM METAL-HYDROCHLORIC ACID SYSTEM
- Reactions of Sodium Borohydride. IV. Reduction of Aromatic Sulfonyl Chlorides with Sodium Borohydride(Organic,Chemical)
- Studies of Reduction of Various Organic Compounds with the Nickel(II) Chloride-Zinc System
- Studies of Reduction with Dimethoxyborane-Transition Metal Boride Systems
- Selective Reduction of Aromatic Nitro Compounds with Nickel Boride
- Studies of Reduction with Dimethoxyborane-Transition Metal Salt Systems. I. : Reduction of Nitriles, Aldehydes and Ketones with Dimethoxyborane-Transition Metal Salt Systems
- Studies of Reduction with the Sodium Borohydride-Transition Metal Boride System. I. : Reduction of Nitro and the Other Functional Groups with the Sodium Borohydride-Nickel Boride System
- Selective Reduction of Imines with the Diborane-Methanol System
- Reactions of Trialkylborane. VI. : Reduction of Carbonyl Compounds with Trialkylborane
- Studies of Reduction with the Diborane-Transition Metal Salt system
- Reduction of Heterocyclic Compounds. II. Reduction of Heterocyclic Compounds with Sodium Borohydride-Transition Metal Salt Systems