遷移金属錯イオンの吸収スペクトルについて
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概要
- 論文の詳細を見る
The effects of vibration-electronic interaction in the octahedral complexes are discussed from the point of view of the crystalline field theory. Based on a simple model for the potential energy of the nuclei, all normal modes of an octahedral MX_6 complex are determined explicitly. A general formula is derived for the probability of the electronic transition between the states of the same parity brought about by the vibration-electronic interaction. An approximate treatment is proposed for the calculation of the influence exerted upon the spectral intensity by the partial substitution of the ligands. Group theoretical tables useful for the study of these problems are compiled for reference.
- 東京女子大学の論文