Function of an N-Heterocyclic Carbene Ligand Based on Concept of Chiral Mimetic
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概要
- 論文の詳細を見る
Function of a new N-heterocyclic carbene ligand based on the concept of a chiral mimetic is described. With (4R, 5R)-4,5-diphenyl-1,3-dialkyl-4,5-dihydro-3H-imidazol-1-ium tetrafluoroborates as N-heterocyclic carbene precursors, Rh-catalyzed enantioselective arylation (up to 27% ee) of aromatic aldehydes with arylboronic acids and Pd-catalyzed enantioselective intramolecular α-arylation (up to 66% ee) of N-(2-bromoaryl)-N-alkyl-2-aryl-propanamides are investigated.
- 公益社団法人日本薬学会の論文
- 2006-11-01
著者
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Sato Kei
Graduate School Of Pharmaceutical Sciences Nagoya City University
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Kondo Kazuhiro
Graduate School Of Pharmaceutical Sciences Nagoya City University
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ARAO Takafumi
Graduate School of Pharmaceutical Sciences, Nagoya City University
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AOYAMA Toyohiko
Graduate School of Pharmaceutical Sciences, Nagoya City University
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Arao Takafumi
Graduate School Of Pharmaceutical Sciences Nagoya City University
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Aoyama Toyohiko
Graduate School Of Pharmaceutical Sciences Nagoya City University
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