THE CONCEPT OF RACEMATES AND THE SOAI-REACTION(<特集>ISOLAB'05 プロシーディング)
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概要
- 論文の詳細を見る
The traditional concept of racemates means an exactly 1:1 mixture of two enantiomeric molecules. Modern analytical and catalytic/preparative discoveries, first of all the Soai-reaction, make necessary a re-evaluation of this concept. The most important aspect of such a revision is the definition of the amount of an excess of one or of the other enantiomer, originating from statistical fluctuation, which can still be "tolerated" when a substance is defined as racemate. The present paper discusses the statistical view of racemates and some related problems.
- 生命の起原および進化学会の論文
- 2006-07-07
著者
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Caglioti Luciano
Department Of Chemistry And Technology Of Biologically Active Compounds University "la Sapienza
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Hajdu Csongor
Department of Inorganic and Analytical Chemistry, University of Debrecen
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Holczknecht Orsolya
Department of Inorganic and Analytical Chemistry, University of Debrecen
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Zekany Laszlo
Department of Inorganic and Analytical Chemistry, University of Debrecen
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Zucchi Claudia
Department of Chemistry, University of Modena and Reggio Emilia
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Micskei Karoly
Department of Inorganic and Analytical Chemistry, University of Debrecen
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Palyi Gyula
Department of Chemistry, University of Modena and Reggio Emilia
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Palyi Gyula
Department Of Chemistry University Of Modena And Reggio Emilia
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Hajdu Csongor
Department Of Inorganic And Analytical Chemistry University Of Debrecen
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Zekany Laszlo
Department Of Inorganic And Analytical Chemistry University Of Debrecen
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Micskei Karoly
Department Of Chemistry University Of Debrecen
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Zucchi Claudia
Department Of Chemistry University Of Modena And Reggio Emilia
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Holczknecht Orsolya
Department Of Inorganic And Analytical Chemistry University Of Debrecen:department Of Chemistry Univ
関連論文
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