Reaction of Aromatic Alcohols with Phosphorous Pentasulfide
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概要
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The reaction of aromatic alcohols and phosphorous pentasulfide has been studied. Primary alcohols and some of the secondary alcohols bearing aryl and alkyl groups yielded O, O-diaralkyl hydrogen phosphorodithioates as primary product and these acid esters decomposed easily by heat to give hydrogen sulfide, mercaptans, thioethers and unsaturated hydrocarbons. While the secondary alcohols containing only aryl groups and tertiary alcohols gave only unsaturated hydrocarbons.
- 東北大学の論文