Synthesis of Norbornene Anhydride-Mercury Compound and Its Nucleophilic Reaction

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概要

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• 5-Norbornene anhydride-mercury compound (III) was synthesized. Since its infrared spectrum showed the shift of carbonyl absorption to a very low wave number side, O-Hg linkage was considered to be in an ionic form (III'), with the carbon in the bonded to mercury becoming a carbonium ion, suggesting the likelihood of its reaction with nucleophilic reagents. Reactions of III with nucleophilic reagents showed that III is reactive to H_2S, KI, and KCN.

• 公益社団法人日本薬学会の論文
• 1979-04-25

著者

• 鷹觜 照男

  Faculty Of Pharmaceutical Sciences Toho University

関連論文

• Syntheses of Diphenic Anhydride-Mercury Compounds and Their Reaction with Nucleophilic Reagents
• Synthesis of Mercurated Pyridine-3-carboxylic Anhydride and Its Reaction with Nucleophilic Reagents
• Synthesis of Norbornene Anhydride-Mercury Compound and Its Nucleophilic Reaction

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