Synthesis of Mercurated Pyridine-3-carboxylic Anhydride and Its Reaction with Nucleophilic Reagents

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概要

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• Mercurated pyridine-3-carboxylic anhydride (III), obtained by the reaction of pyridine-2,3-dicarboxylic acid with mercuric oxide, showed a carbonyl absorption in the IR spectrum at extremely low wave number, indicating that the oxygen-mercury bond is ionic in nature, and thus that compound (III) takes an ionic structure (III'). The carbon bonded with mercury is reactive with nucleophilic reagents (SH^-, CN^-, I^-), as would be expected.

• 1979-10-25

著者

• 鷹觜 照男

  Faculty Of Pharmaceutical Sciences Toho University

関連論文

• Syntheses of Diphenic Anhydride-Mercury Compounds and Their Reaction with Nucleophilic Reagents
• Synthesis of Mercurated Pyridine-3-carboxylic Anhydride and Its Reaction with Nucleophilic Reagents
• Synthesis of Norbornene Anhydride-Mercury Compound and Its Nucleophilic Reaction

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