Rearrangement of Sulfonamide Derivatives. VIII. Kinetics of the Rearrangement Reaction of Sulfonamide Derivatives with Alkali.

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概要

• 論文の詳細を見る

• Reaction rates of N-acetoacetyl, N-cyanoacetyl, and N-phenylacetyl derivatives of o- and p-nitrobenzenesulfonamide and 2- and 4-pyridinesulfonamide 1-oxides with alkali were compared. Rate coefficients, heat constants of activation, and entropies of activation were calculated. Pyridinesulfonamide 1-oxide derivatives reacted faster than nitrobenzene derivatives and reactivities of N-phenylacetyl derivatives were smallest.

• 公益社団法人日本薬学会の論文
• 1964-05-25

著者

• 堂森 廉三

  Central Research Laboratory, Daiichi Seiyaku Co., Ltd.

• 堂森 廉三

  Central Research Laboratory Daiichi Seiyaku Co. Ltd.

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• Rearrangement of Sulfonamide Derivatives. V. Syntheses of Methyl α-Phenyl-2- and 4-piperidineacetate.
• Rearrangement of Sulfonamide Derivatives. VIII. Kinetics of the Rearrangement Reaction of Sulfonamide Derivatives with Alkali.
• Rearrangement of Sulfonamide Derivatives, VII. Rearrangement Reaction of the Sulfonamide Derivatives of Pyridine 1-Oxide at a Room Temperature.
• Rearrangement of Sulfonamide Derivatives. VI. Rearrangement Reaction of N-Acetoacetyl-p-methyl-sulfonylbenzenesulfonamide with Alkali.

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