PREPARATION AND REACTION OF NOVEL OXYGEN ESTER ENOLATES, 1, : REACTION OF THIOGLYCOLATE WITH ALDEHYDES USING DIALKYLBORYL TRIFLATE
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With the assistance of the electron withdrawing effect of divalent sulfur substituent, boron ester enolates were formed from the corresponding oxygen esters in the presence of dialkylboryl trifluoromethanesulfonate. These novel oxygen ester enolates reacted smoothly with aldehydes to produce the usual syn-aldol products.
- 1988-11-25
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- PREPARATION AND REACTION OF NOVEL OXYGEN ESTER ENOLATES, 2,REACTION OF GLYCOLATE WITH ALDEHYDES USING DIALKYLBORYL TRIFLATE
- PREPARATION AND REACTION OF NOVEL OXYGEN ESTER ENOLATES, 1, : REACTION OF THIOGLYCOLATE WITH ALDEHYDES USING DIALKYLBORYL TRIFLATE