窒素含有糖類(第8報) : 1-デオキシ-1-ニトロアルコールのメチルおよびアセチル誘導体の円二色性と旋光分散(有機化学)

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概要

• 論文の詳細を見る

• Circular dichroism (CD) and optical rotatory dispersion of 1-deoxy-2-O-methyl-1-nitro-D-mannitol and four acetyl derivatives of 1-deoxy-1-nitro alcohols were measured. Their CD curves showed maxima (or shoulders) at about 310 mμ and 280 mμ. It was found that the rules relating the configuration at C-2 of 1-deoxy-1-nitro-alcohols to the signs of their CD maxima also applied to these compounds, i.e., compounds that have an acetoxyl group on the left side of C-2 in the conventional Fischer projection formula showed negative maxima, whereas those having the acetoxyl group on the right side of C-2 showed positive maxima. However, 2,3,4,5,6,7-hexa-O-acetyl-1-deoxy-1-nitro-D-glycero-L-glucoheptitol, which has a C-2 acetoxyl group on the left side, showed a negative CD maximum at 314 mμ and a positive CD maximum at 284 mμ.

• 公益社団法人日本薬学会の論文
• 1972-02-25

著者

• 清本 昭夫

  田辺製薬株式会社生物研究所

• 佐藤 千代子

  田辺製薬株式会社生物研究所

関連論文

• 窒素含有糖類(第8報) : 1-デオキシ-1-ニトロアルコールのメチルおよびアセチル誘導体の円二色性と旋光分散(有機化学)
• 窒素含有糖類(第7報) : 1,2-ジデオキシ-1-ニトロアルコールアセテートの円二色性(有機化学)
• Studies on the Optical Rotatory Dispersion of Carbohydrate C-Nitroalcohols
• Studies on Trimetoquinol. II. The Metabolic Fate of Trimetoquinol
• (−)-1-(3, 4, 5-trimethoxybenzyl)-7-hydroxy-1, 2, 3, 4-tetrahydroisoquinoline HCl(l-MTI)の気管支拡張作用

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