Studies on an Antibiotic, Albocycline. V. High Pressure-High Temperature Hydrogenation Products, and Structure Proof of Albocycline

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概要

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• By the catalytic hydrogenation of albocycline in acetic acid under high pressure at elevated temperature, nine reaction products were obtained. They were classified into pairs by their infrared (IR), nuclear magnetic resonance (NMR) and mass spectral data. The eluci dation of structures of these pair products gave the conclusive answers about the positions of O-functions, especially that of a methoxy group, in albocycline molecule. Thus, the structure of albocycline was finally confirmed as Ia.

• 公益社団法人日本薬学会の論文
• 1971-04-25

著者

• 鈴木 真言

  Microbial Chemistry Research Laboratory Tanabe Seiyaku Co. Ltd.

• 長浜 昇

  Microbial Chemistry Research Laboratory, Tanabe Seiyaku Co., Ltd.

• 高森 勲

  Microbial Chemistry Research Laboratory, Tanabe Seiyaku Co., Ltd.

• 長浜 昇

  Microbial Chemistry Research Laboratory Tanabe Seiyaku Co. Ltd.

• 高森 勲

  Microbial Chemistry Research Laboratory Tanabe Seiyaku Co. Ltd.

関連論文

• Studies on an Antibiotic, Albocycline. III. Partial Structure of Albocycline
• Studies on an Antibiotic, Albocycline. V. High Pressure-High Temperature Hydrogenation Products, and Structure Proof of Albocycline
• Studies on an Antibiotic, Albocycline. IV. Catalytic Hydrogenation and Structure Elucidation of Albocycline
• 6 ナルボマイシンおよびピクロマイシンの生合成

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