Functionalization Including Fluorination of Nitrogen-Containing Compounds Using Electrochemcial Oxidation
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概要
- 論文の詳細を見る
Nitrogen-containing compounds have been subjected to electrochemical oxidation with Et_3N-3HF as an electrolyte. Caffeine afforded 8-fluorocaffeine as a sole product in 40.3% yield. Guanosine tetraacetate and uridine triacetate gave the fluorinated compounds in 17.5 and 4.6% yields, rspectively. Similar electrochemical oxidation of caffeine with methanol, KCl, or KCN afforded 8-methoxycaffeine, 8-chlorocaffeine, or 8-cyanocaffeine, respectively.
- 公益社団法人日本薬学会の論文
- 1996-06-15
著者
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TORI Motoo
Faculty of Pharmaceutical Sciences, Tokushima Bunri University
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Tori Motoo
Faculty Of Pharmaceutical Sciences Tokushima Bunri University
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Shimizu Kahori
Faculty Of Pharmaceutical Sciences Tokushima Bunri University
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SHIZURI Yoshikazu
Faculty of Pharmaceutical Sciences, Tokushima Bunri University
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Shizuri Yoshikazu
Faculty Of Pharmaceutical Sciences Tokushima Bunri University
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Toyoda Naoko
Faculty Of Pharmaceutical Sciences Tokushima Bunri University
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Sono Masakazu
Faculty Of Pharmaceutical Sciences Tokushima Bunri University
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NODA Eiji
Faculty of Pharmaceutical Sciences, Tokushima Bunri University
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Noda Eiji
Faculty Of Pharmaceutical Sciences Tokushima Bunri University
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