THREE TETRAHYDROISOQUINOLINE-MONOTERPENE GLUCOSIDES FROM ALANGIUM LAMARCKII : THE FIRST OCCURRENCE OF GLUCOSIDES WITH THE SAME ABSOLUTE CONFIGURATIONS AS DEACETYLISOIPECOSIDE, A KEY INTERMEDIATE IN THE BIOSYNTHESIS OF IPECAC ALKALOIDS
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概要
- 論文の詳細を見る
From the fruits of Alangium lamarckii, three new tetrahydroisoquinoline-monoterpene glucosides, isoalangiside, 3-O-demethyl-2-O-methylisoalangiside and methylisoalangiside, were isolated. Their structures were determined by spectroscopic and chemical methods. This is the first instance of the isolation of glucosides with the same absolute configurations as deacetylisoipecoside, and strongly supports the intermediacy of the latter compound in ipecac alkaloid biosynthesis.
- 公益社団法人日本薬学会の論文
- 1994-10-15
著者
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棚橋 孝雄
神戸薬大
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棚橋 孝雄
Kobe Women's College of Pharmacy
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永倉 直敬
Kobe Women's College of Pharmacy
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伊藤 篤子
神戸薬科大学
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伊藤 篤子
Kobe Pharmaceutical University
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永倉 直敬
Kobe Women's College Of Pharmacy
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永倉 直敬
Kobe Pharmaceutical University
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