Studies on Thiohydroxamic Acids and Their Metal Chelates. VII. Syntheses of Some Compounds Possessing Mercapto and Hydroxyimino Groups and Their Reactivities with Metal Ions
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Several compounds possessing both mercapto and hydroxyimino groups, such as 2-mercaptoacetophenone oxime, 3-mercaptopropiophenone oxime and 5-nitro-2-mercapto-benzaldehyde oxime, were prepared, and their reactivities with metal ions were compared with those of the corresponding ketones or aldehyde and those of thiohydroxamic acids. It was found that these compounds did not show any sensitive color reactions with Fe^<3+>, Ti^<4+>, UO^<2+>_2 and VO^<2+> and did not form stable Fe^<3+> and Cu^<2+> complexes, differing from thiohydroxamic acids, and that the conversions of the compounds possessing both carbonyl and mercapto group to the corresponding oximes did not give any effect on the sensitivities and selectivities.
- 公益社団法人日本薬学会の論文
- 1969-04-25
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関連論文
- Studies on Thiohydroxamic Acids and Their Metal Chelates. VII. Syntheses of Some Compounds Possessing Mercapto and Hydroxyimino Groups and Their Reactivities with Metal Ions
- Studies on Thiohydroxamic Acids and Their Metal Chelates. VI. Some Reactions of Metal Complexes of Thiohydroxamic Acids
- Studies on Thiohydroxamic Acids and Their Metal Chelates. V. Infrared Spectra of Metal Chelates of Thiohydroxamic Acids
- Studies on Thiohydroxamic Acids and Their Metal Chelates. IV. Reaction of Thiohydroxamic Acids with Metal Ions
- Studies on Thiohydroxamic Acids and Their Metal Chelates. III. Syntheses of Some Thiohydroxamic Acid Derivatives and Their Structures
- Studies on Thiohydroxamic Acids and Their Metal Chelates. II. Structures of Thiohydroxamic Acids
- Studies on Thiohydroxamic Acids and Their Metal Chelates. I. Syntheses of Thiohydroxamic Acids and O-Methyl-thiohydroxamic Acids