Studies on Thiohydroxamic Acids and Their Metal Chelates. V. Infrared Spectra of Metal Chelates of Thiohydroxamic Acids
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概要
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The infrared spectra of some metal salts of thiohydroxamic acids (I) and O-methyl-thiohydroxamic acids (II) were investigated, and it was decided that the salts have the structures including oxime group, [chemical formula] M^<+n> (M=Metal ion), by deuteration method. From the comparisons of the band frequencies which are attributed to the oxime group with those of the corresponding derivatives (S-methyl derivatives and disulfides of I or II) it was shown that some transition metal salts have the chelate structures. Although it was difficult to decide finally whether the chelate structures are the S-O coordinated or the S-N coordinated type, the former seemed to be more probable.
- 公益社団法人日本薬学会の論文
- 1967-01-25
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関連論文
- Studies on Thiohydroxamic Acids and Their Metal Chelates. VII. Syntheses of Some Compounds Possessing Mercapto and Hydroxyimino Groups and Their Reactivities with Metal Ions
- Studies on Thiohydroxamic Acids and Their Metal Chelates. VI. Some Reactions of Metal Complexes of Thiohydroxamic Acids
- Studies on Thiohydroxamic Acids and Their Metal Chelates. V. Infrared Spectra of Metal Chelates of Thiohydroxamic Acids
- Studies on Thiohydroxamic Acids and Their Metal Chelates. IV. Reaction of Thiohydroxamic Acids with Metal Ions
- Studies on Thiohydroxamic Acids and Their Metal Chelates. III. Syntheses of Some Thiohydroxamic Acid Derivatives and Their Structures
- Studies on Thiohydroxamic Acids and Their Metal Chelates. II. Structures of Thiohydroxamic Acids
- Studies on Thiohydroxamic Acids and Their Metal Chelates. I. Syntheses of Thiohydroxamic Acids and O-Methyl-thiohydroxamic Acids