Studies on the Synthesis of Amino Acids by the Schmidt Reaction. II. New Synthetic Method for ω-Amino Acids and Syntheses of DL-2,8-Diaminooctanoic Acid and DL-2,9-Diaminononanoic Acid.
スポンサーリンク
概要
- 論文の詳細を見る
A new method was found for synthesis of ω-amino acids in a good yield by the Schmidt reaction, reacting basic acids with calculated amount of hydrazoic acid. In this case, the use of monoalkyl ester of dibasic acid as the starting material gave still better yield. In addition, DL-2,8-diaminooctanoic acid and DL-2,9-diaminononanoic acid were obtained in a high yield as their monohydrochlorides from 8-aminooctanoic acid and 9-aminononanoic acid, respectively, which were prepared by the above-mentioned reaction.
- 公益社団法人日本薬学会の論文
- 1959-02-10
著者
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高木 誠司
Pharmaceutical Institute Medical Faculty University Of Kyoto
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林 恭三
Pharmaceutical Institute Medical Faculty. University Of Kyoto
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- Studies on the Synthesis of Amino Acids by the Schmidt Reaction. IV. Synthesis of DL-Homoserine.
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- Studies on the Synthesis of Amino Acids by the Schmidt Reaction. II. New Synthetic Method for ω-Amino Acids and Syntheses of DL-2,8-Diaminooctanoic Acid and DL-2,9-Diaminononanoic Acid.
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