Enantioselective Synthesis of (-)-Vertinolide

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概要

• 論文の詳細を見る

• (-)-Vertinolide, a β-tetronic acid derivative isolated from Verticillium intertextum as one of the mycotoxins, was synthesized starting from (R)-lactic acid as the chiral source by using Seebach's chiral self-reproduction method. The β-tetronic acid moiety was constructed by reductive dehydroxylation of α, β-dihydroxybutanolide with samarium(II) iodide and subsequent oxdation.

• 公益社団法人日本薬学会の論文
• 1997-10-15

著者

• MATSUO Keizo

  Faculty of Pharmaceutical Sciences, Kinki University

• Matsuo Keizo

  近畿大学 薬

• Sakaguchi Yusuke

  Faculty Of Pharmaceutical Sciences Kinki University

• Matsuo Kazuya

  Pharmaceutical Research Laboratory Hokuriku Seiyaku Co. Ltd.:department Of Pharmaceutics Kanazawa Un

• Matsuo Keizo

  Faculty Of Pharmaceutical Sciences Kinki University

関連論文

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• Anti-androgenic Activity of Myricae Cortex-Isolation of Active Constituents from Bark of Myrica rubra
• Racemization Kinetics of Meluadrine Tartrate in Aqueous Solution
• Synthesis of a Key Intermediate for the Synthesis of (+)-Grandisol Utilizing (-)-Quinic Acid
• Enantioselective Synthesis of (-)-Vertinolide
• Synthetic studies on terpenic compounds. XII. Selective degradation of the side chain in portulal.

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