The Inclusion Compound of a New Ionizable Derivative of β-Cyclodextrin with Ferrocenium Drug

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概要

• 論文の詳細を見る

• A new β-cyclodextrin (β-CD) derivative, mono[6-dexoy-6-(2-butenedinitrile-2, 3-dimercapto sodium salt]-β-CD (6-mnt-β-CD), and its inclusion compound with a ferrocenium drug, have been prepared and characterized by IR, UV, ^<13>C-NMR spectroscopy, and mass spectrometry, elemental analysis, thermogravimetry, and cyclic voltammetry (CV). The interplay between the side-arm anion of β-CD and the ferrocenium (guest) in the inclusion compound 6-mnt-β-CD^-/Fc^+ has been investigated by ^<13>C-NMR, UV, IR, and thermogravimetric methods. Charge transfer from the anion to the cation in 6-mnt-β-CD^-/Fc^+ was then experimentally identified. The interaction between the guest and the host with side-arm in 6-mnt-β-CD^-/Fc^+ resulted in samller positive potential shifts compared to that in the inclusion compound [β-CD^/FC^+]BF^-_4.

• 公益社団法人日本薬学会の論文
• 2001-07-01

著者

• Lu C‐s

  Nanjing Univ. Nanjing Chn

• Zhu Hui-zhen

  Coordination Chemistry Institute State Key Laboratory Of Coordination Chemistry Nanjing University

• LU Chang-Sheng

  Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University

• REN Xiao-Ming

  Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University

• HU Chuan-Jiang

  Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University

• MENG Qing-Jin

  Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University

• Meng Qing-jin

  Coordination Chemistry Institute State Key Laboratory Of Coordination Chemistry Nanjing University

• Hu Chuan-jiang

  Coordination Chemistry Institute State Key Laboratory Of Coordination Chemistry Nanjing University

• Lu Chang-sheng

  Coordination Chemistry Institute State Key Laboratory Of Coordination Chemistry Nanjing University

• Ren Xiao-ming

  Coordination Chemistry Institute State Key Laboratory Of Coordination Chemistry Nanjing University

関連論文

• The Inclusion Compound of a New Ionizable Derivative of β-Cyclodextrin with Ferrocenium Drug
• An Antitumor Agent of β-Cyclodextrin-Modified Titanocene Complex: Synthesis and Characterization
• The Inclusion Compounds of β-Cyclodextrin with 4-Substituted Benzoic Acid and Benzaldehyde Drugs Studied by Proton Nuclear Magnetic Resonance Spectroscopy

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