Water-Soluble Porphyrins Appending Platinum(II) Complexes as Binders for Synthetic Nucleic Acid Polymers

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概要

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• Water-soluble porphyrins containing four platinum(II) complexes per molecule, |5α,10β,15α,20β-tetrakis(2-trans-(α,β,α,β-trans-Pt) and cis-(α,β,α,β-cis-Pt) [PtCl(NH_3)_2 N-2-amino-phenylporphyrin)], were synthesized and characterized. The binding of synthetic nucleotide polymers (poly(dG)-poly(dC), poly(dA)-poly(dT)) to the porphyrins was examined spectrophotometrically in aqueous solution. UV-vis spectral data suggested that these porphyrins bind to the nucleic acids by coordinative and Coulomb interactions.

• 公益社団法人日本薬学会の論文
• 2003-05-01

著者

• Nakagawa S

  Faculty Of Science Himeji Institute Of Technology

• Imai H

  Faculty Of Pharmaceutical Sciences Hokuriku University

• Uemori Y

  Faculty Of Pharmaceutical Sciences Hokuriku University

• Nakagawa S

  Computing Services Center Hokuriku University

• IMAI Hiroyasu

  Faculty of Pharmaceutical Sciences, Hokuriku University

• MUNAKATA Hiroki

  Faculty of Pharmaceutical Sciences, Hokuriku University

• UEMORI Yoshio

  Faculty of Pharmaceutical Sciences, Hokuriku University

• NAKAGAWA Shigeo

  Computing Services Center, Hokuriku University

• OSADA Atsuko

  Faculty of Pharmaceutical Sciences, Hokuriku University

• Munakata H

  Faculty Of Pharmaceutical Sciences Hokuriku University

• Osada Atsuko

  Faculty Of Pharmaceutical Sciences Hokuriku University

• Uemori Yoshio

  Faculty Of Pharmaceutical Sciences Hokuriku University

• Imai Hiroyasu

  Department Of Pharmaceutical Science School Of Pharmacy Hokuriku University

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• REVERSIBLE OXYGENATION OF "PICKET FENCE"-TYPE PORPHYRINATOCOBALT (II) COMPLEXES
• Water-Soluble Zinc Porphyrins as Artificial Receptors for Amino Acids
• Binding Enhancements of Nicotinic Acid to Water-Soluble Zinc Porphyrins Based on Triple Attractions of Coordination, Coulomb, and CH-π Interactions
• Water-Soluble Porphyrins Appending Platinum(II) Complexes as Binders for Synthetic Nucleic Acid Polymers
• Synthesis and Nucleic Acid-Binding Properties of Water-Soluble Porphyrins Appending Platinum(II)Complexes
• Water-Soluble Zinc Porphyrins as Receptors for Amino Carboxylates
• Synthesis and Axial-Ligand Binding of Zinc Complexes of Amphiphilic Porphyrins Containing a Hydrophobic Binding Pocket
• ELECTROSTATIC DIOXYGEN-LIGAND INTERACTIONS IN OXY COBALTMYOGLOBIN MODEL COMPLEXES

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