Synthesis of Optically Active α-Isopropyl-4-substituted Phenylacetic Acids by Asymmetric Hydrogenation

スポンサーリンク

概要

• 論文の詳細を見る

• Homogeneous hydrogenation of 2-phenyl-3-methyl-2-butenoic acid derivatives in the presence of a catalytic amount of such chiral phosphine-rhodium complexes as Rh/(R)-BINAP, Rh/(R)-, or (S)-Cy-BINAP, Rh/(R)-p-tolyl-BINAP, and Rh/(R)-p-methoxy-phenyl-BINAP afforded the corresponding phenylacetic acid de-rivatives in high enantiomeric excesses and in quantitative chemicalyields. The optically active phenylacetic acid derivatives are useful intermediates of agrochemicals and pharmaceuticals.

• 社団法人日本農芸化学会の論文
• 1994-11-23

著者

• Kawamura Norio

  Organic Synthesis Research Laboratory Sumitomo Chemical Co. Ltd.

• Takemoto Ichiki

  Organic Synthesis Research Laboratory, Sumitomo Chemical Co., Ltd.

• Kaminaka Hiroshi

  Organic Synthesis Research Laboratory, Sumitomo Chemical Co., Ltd.

• Takemoto Ichiki

  Organic Synthesis Research Laboratory Sumitomo Chemical Co. Ltd.

• Kaminaka Hiroshi

  Organic Synthesis Research Laboratory Sumitomo Chemical Co. Ltd.

関連論文

• Synthesis of Optically Active α-Isopropyl-4-substituted Phenylacetic Acids by Asymmetric Hydrogenation
• Synthesis of a Fluorobenzoxazine Derivative and Its Analogues
• Selective Synthesis of Fluorophenol Derivatives

スポンサーリンク