EFFECT OF PRESSURE ON THE VISCOSITY B COEFFICIENT OF CESIUM CHLORIDE IN WATER
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概要
- 論文の詳細を見る
Viscosity of aqueous cesium chloride(CsCl)solution was measured in the ranges of 0.1-5.0 mol kg^<-1> and 0.1-375Mpa at 283.2 and 323.2K. The jones-Dole B coefficient of CsCl increased with increasing pressure and then decreased passing over a maximum as well as previously observed one at 298.2K. The maximum B became more remarkable with decreasing temperature from 323.2K. These phenomena were compared with the dielectric friction theory supposing solvent water as a continuum fluid. Inconsistency of the theory at low pressure suggested an existence of any structure in water. Pressure dependence of B is ascribed to a balance between the water structure and the dielectric friction effect.
- 社団法人日本材料学会の論文
- 1996-09-15
著者
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TANIGUCHI Yoshihiro
Department of Pediatrics, Fukui Red Cross Hospital
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Sawamura Seiji
Department Of Chemistry Faculty Of Science And Engineering Ritsumeikan University
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Nakai Takehiro
Department Of Chemistry Faculty Of Science And Engineering Ritsumeikan University
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Yamaura Yuichi
Japan Space Utilization Promotion Center
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Taniguchi Yoshihiro
Department Of Chemistry Faculty Of Science And Engineering Ritsumeikan University
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Taniguchi Yoshihiro
Department Of Applied Chemistry Faculty Of Science And Engineering Ritsumeikan University
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