SYNTHESES AND CHARACTERIZATION OF GRAPHITE-LIKE MATERIAL OF COMPOSITION BC_6N_2(H)

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概要

• 論文の詳細を見る

• A new graphite-like layered material of composition BC_6N_2(H) is synthesized by the pyrolysis of (CH_2CHCN)_2:BCl_3 adduct, which is prepared by the interaction of acrylonitrile with boron trichloride at room temperature.X-ray diffraction and UV-Visible spectroscopic analysis suggest that the adduct has a cubic or quasi-cubic structure and is gradually polymerized at room temperature.A possible arrangement in a layer of BC_6N_2 has been considered on the basis of ESCA spectra and chemical interactions among the starting materials, being composed of a unit structure N-C-C-C-C-C-C-N-B.BC_6N_1.5(H) film prepared by CVD reaction (CH_2CHCN:BCl_3=2:1) has a conductivity of 5.31×10~4 S/m at room temperature and behaves as a semiconductor.The reduction of BC_6N_1.5(H) with Li~+C_10H_8~-/THF solution has yielded a lithium intercalated compound with a repeat distance of 0.87nm.

• 社団法人日本材料学会の論文
• 1997-06-15

著者

• KAWAGUCHI Masayuki

  Department of Materials Science, Osaka Electro-Communication University

• Kawaguchi Masayuki

  Department Of Materials Science Osaka Electro-communication University

• Kawaguchi Masayuki

  Department Of Chemistry And Biotechnology Graduate School Of Engineering The University Of Tokyo

• SUGIYAMA Akinari

  Department of Materials Science, Osaka Electro-Communication University

• Sugiyama Akinari

  Department Of Materials Science Osaka Electro-communication University

関連論文

• Preparation and Properties of a New Hard Material of Composition C_3N_O_H_
• Synthesis, Characterization, and Reactivities of Heterobimetallic μ-Aryl Isocyanide Complexes with an Unusual Bridging Structure
• SYNTHESES AND CHARACTERIZATION OF GRAPHITE-LIKE MATERIAL OF COMPOSITION BC_6N_2(H)
• Preparation of graphite intercalation compounds of thiazyl salts.
• The preparation of poly(dicarbon monofluoride) via the graphite intercalation compound.

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