Oriented Process Induced by Dynamically Regulated Energy Barriers(General)
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概要
- 論文の詳細を見る
A novel mechanism for inducing oriented processes is investigated with a flexible system exhibiting barrier-overcoming dynamics. Without any external switching of potentials, multidimensional flexible dynamics promote the oriented processes under nonequilibrium conditions, where reaction paths deviate from those at equilibrium with an accompanying violation of symmetry between the forward and the reverse paths. Along each path, distinct bottleneck points are proposed as a rate-controlling factor. The direction-dependent activation energies evaluated from the actual potential energies at these points are found to satisfy Arrhenius-like law for the rate constants.
- 社団法人日本物理学会の論文
- 2005-06-15
著者
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KOMATSU Teruhisa
Department of Applied Physics, The University of Tokyo
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Nakagawa Naoko
Department Of Information And Media Sciences The University Of Kitakyusyu
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Nakagawa Naoko
Department Mathematical Sciences Ibaraki University
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Nakagawa Naoko
Department Of Mathematical Sciences Ibaraki University:laboratoire De Physique Ens-lyon
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Komatsu Teruhisa
Department Of Applied Physics The University Of Tokyo
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Komatsu Teruhisa
Department Of Physics Gakushuin University
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