Estimation of Column Calibration Factor and Force Parameters to Predict Temperature Dependence of Thermal Diffusion Factor of Some Simple Molecules

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概要

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• The column calibration factor (CCF) F, of a column (Roes and Rutherford 1969) has beenaccurately estimated to yield the thermal diffusion factor ox's of Kr" -Kr", Xe"' -Xe"', CO"CO", CH,['-CH4" and N:'-N:' respectively at two different experimental temperatures. Theprobable temperature dependence of ox's are used to obtain the force pararneters ejj/k andojj of the respective molecules. Again, the o-j?'s as obtained from lnq.... and F, are comparedwith the experimental ax's by the existing method involved with column shape factors as well astheoretical (IT'S based on elastic and inelastic collisions among the molecttles. The comparison ofthe estimated force parameters with the reported ones finally suggests the technique of predictinga-p's as a function of temperature is extremely useful.

• 社団法人日本物理学会の論文
• 1996-08-15

著者

• Chatterjee A

  Department Of Physics Sudarsanpur D.p.u.

• Nandi N

  Raiganj Coll. West Bengal Ind

• Chatterjee A.k.

  Department Of Physiology Calcutta University College Of Science

• Ghosh N.

  Department of Obstetrics & Gynaecology and Endocrinology, Postgraduate Institute of Medical Educatio

• Ghosh N

  Raiganj Coll. West Bengal Ind

• DASGUPTA G.

  Department of Physics,Sudarsanpur D.P.U.

• NANDI N.

  Department of Physics,Sudarsanpur D.P.U.

• ACHARYYA S.

  Department of Physics,Sudarsanpur D.P.U.

• Acharyya S.

  Department Of Physics Sudarsanpur D.p.u.

• Dasgupta G.

  Department Of Physics Sudarsanpur D.p.u.

• CHATTERJEE A.K.

  Department of Physics,Sudarsanpur D.P.U.

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• Thermal Diffusion Factors of Inert Gas Mixtures of Natural Isotopic Abundances in Terms of Column Calibration Factor
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