Extension of High Polymer Molecule and Energy Change by Mixing
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概要
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The change in intermolecular potential energy produced by mixing some low molecular liquids, which are considered as the substitute for the chain elements of polystyrene molecule, with several non-polar solvents and the extension of polystyrene molecule in these solvents were measured, and the obtained results were compared with the theory^(1). Determination of the energy change was made by means of calorimetric method and that of the extension of polystyrene by measuring the intrinsic viscosity of the solution. We found that the variation of the extensions of polystyrene in different non-polar solvents is mainly determined by the difference in the energy change effected by the mixing of benzene, the side group of polystyrene, with the solvents.
- 社団法人日本物理学会の論文
- 1961-02-05
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