Paramagnetic Susceptibility of CoCl_2・6H_2O and its Deuterated Salts
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概要
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The paramagnetic susceptibility of a single crystal of CoCl_2・6H_2O was measured by the usual a-c bridge method. Transition to the antiferromagnetic state was observed at about 3.3°K. The easy axis is along the crystalline c axis. The g values determined in the paramagnetic region, below 20°K are: g_o = g_b = 4.9 and g_<o1> = 2.9. Some considerations about the anisotropic susceptibilities in the paramagnetic state are given from the standpoint of crystalline field theory. The exchange interaction in this salt is discussed considering the interaction path between the magnetic ions which involves the linkages of chlorine atoms or water molecules. The measurements on the deuterated salts are intended to make clear the effect of the hydrogen bond on the magnetic exchange interaction.
- 社団法人日本物理学会の論文
- 1960-03-05
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