Perturbed Rotational State in Ion-Molecule Collision : Effect of Potential Ridge

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概要

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• The PRS (perturbed rotational state -rotationally adiabatic state) methodis applied to the collision system of an ion and a linear molecule whichpossesses a strong, weak or vanishing dipole moment. The structure of the in-termolecular interaction with a negative quadrupole and a weak dipole momentsis characterized by a ridge and two valleys. This structure has a critical impor-lance for the adiabatic state, as is seen in the cases -the two-electron-excitedstate of atoms and the Rydberg atom in a magnetic field -pointed out by Fano.Consideration of the adiabatic state in the ton-molecule system supplies a clas-sification of polar and weakly-polar molecules.

• 社団法人日本物理学会の論文
• 1982-08-15

著者

• Sakimoto Kazuhiro

  The Institute Of Space And Astronautical Science

関連論文

• Influence of the Dipole Interaction on the Low-Energy Ion-Molecule Reaction [J.Phys.Soc.Jpn.48(1980)2076]
• Perturbed Rotational State in Ion-Molecule Collision : Effect of Potential Ridge
• Semiclassical Decoupling Schemes in Molecular Collisions

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