Studies on Ag^- Centers in Alkali Halides. : I. Nature of Optical Transitions: KCl
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概要
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A study was made on absorption and emission spectra of Ag^- centers in KCl crystals. By inspecting the excitation spectra for emission, two new bands were found at 3.11 and 3.27 eV in addition to the previously known 4.36 eV absorption band. These three bands, named A, B, and C, are ascribed to transitions ^1S_0&roar;^3P_1, ^3P_2 and ^1P_1 respectively. Besides the 2.93 eV emission, another emission band was discovered at 4.08 eV. They are attributed to transitions ^3P_1 and ^1P_1&roar;^1S_0. Energy parameters and electron-lattice coupling constants specifying the configuration-coordinate surfaces were determined from the peak energies, second moments, and Stokes shifts of the observed spectra. Data on the degree of polarization suggest that a trigonal lattice deformation is dominantly realized in each of the relaxed ^1P_1 and ^3P_1 states. The shape of the C band and the ratio of life times for the ^1P_1 and ^3P_1 states are in reasonable agreement with theory.
- 社団法人日本物理学会の論文
- 1970-05-05
著者
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Maki Masako
Second Department Of Physics Faculty Of Science Tohoku University
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Kojima Kazuko
Second Department Of Physics Faculty Of Science Tohoku University
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Kojima Kazuko
Second Department Of Physics Faculty Of Science Tohoku Univerisyt
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Shimanuki Shigetaka
Second Department Of Physics Faculty Of Science Tohoku University
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KOJIMA Tadanobu
Second Department of Physics, Faculty of Science, Tohoku University
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Kojima Tadanobu
Second Department Of Physics Faculty Of Science Tohoku Univerisyt
関連論文
- Studies on Ag^- Centers in Alkali Halides. : IV. Characteristic Features of Ag^- Centers
- On the Nature of the Anomalous Emission C^* in KI:Ag^- and KCl:Ag^-(Li)
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- Studies on Ag^- Centers in Alkali Halides. : II. Ag^-(Na) Centers in KCl
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