Glass Transition of the Solvent in a Polystyrene Gel

スポンサーリンク

概要

• 論文の詳細を見る

• The mechanism of the glass transition of solvent quinoline in a polystyrene(quinoline) get is studied by measurements of get length and depolarized Rayleigh scattering. It is found that the effect of intermolecular force between quinoline moleculesand the polystyrene network is important in the glass transition of the solvent. Due tothe force, fluctuations in orientations of solvent molecules are frozen and themolecules are bound to the network. With nearing the glass transition temperature,the intensity of a broad Rayleigh component decreases due to decrease of the numberof solvent molecules fluctuating in the network and that of a narrow Rayleigh compo-nent increases due to increase of inhomogeneity of the get density.

• 社団法人日本物理学会の論文
• 1987-10-15

著者

• Kato Eiji

  Department Of General Education Kobe University Of Mercentile Marine

関連論文

• Pressure-Induced Critical Point of Ionized N-Isopropylacrylamide Gels
• Vibrational Relaxation in Benzene near the Melting Point
• Dynamical Aspect of Pressure-Induced Phase Separation of N-Isopropylacrylamide Gels
• Glass Transition of the Solvent in a Polystyrene Gel
• A possible role of intracellular Ca2+ in the regulation of the ACh receptor-ion channel complex of the sympathetic ganglion cell.

スポンサーリンク