Rotational Motion of Axially Symmetric Molecules in Liquids
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概要
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After Langevin's method, orientional diffusion of a non-spherical particle is investigated. By use of this method the study of the molecular rotational motion is extended to that of that of axially symmetric molecules, in which the cross terms of angular velocity components are not neglected. The components of the rotational friction coefficient tensor are expressed quite generally. Angular autocorrelation functions are given by use of the distribution function. It is shown that the contribution of the precessional motion is never neglected at small time. The calculated results are compared with the experimental results of infrared absorption measurements.
- 社団法人日本物理学会の論文
- 1971-12-05
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