Mathematical Theory of Polymer Gelation
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概要
- 論文の詳細を見る
A new general theoretical treatment is given concerning the change in molecular size distribution due to crosslinking. Mass conservation and gelation are discussed by this fundamental treatment. The behaviors of the number and weight average molecular size of sol after gelation point are shown for many initial molecular size distributions. When a polymer has such a molecular size distribution as has two peaks, the weight average molecular size of sol may have a maximum and a minimum in the region after gelation point. Polymers which contain gel fraction initially are discussed by the same fundamental treatment as those which contain no gel fraction initially. The latter is the limiting case of the former. New quantities are derived which conserve in the region prior to gelation.
- 社団法人日本物理学会の論文
- 1969-05-05
著者
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Saito Osamu
Department Of Agro-environmental Management Hokkaido National Agricultural Experiment Station
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Saito Osamu
Department Of Physics Faculty Of Science And Engineering Chuo University
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Amemiya Ayao
Department Of Applied Physics The University Of Electro-communications
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Amemiya Ayao
Department Of Applied Mathematics Second Faculty Of Engineering And Department Of Dynamics First Fac
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