Molecular Association in a One-Dimensional Square-Well Fluid
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概要
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1VIolectrlar association of the solute molecules in a one-dimensional sqttare-well fltrid is sttrdiedunder the infinitely dilute condition over 21 wide density regioz'n. A statistical utaechataical f'orrnalisuau of the one-dinaensiot'tal fltrid is given, Different aspects of tlae rnolectrlar association areextracted by several nreastrres strch as the distribtrtion f'tmnction at t[ae coratact distance. Theeffect of the solute-solvent interaction is discttssed in viexv of the rnutnber of tlae "bot'xd" thatis asstrrned for a pair of soltrte and solvent molecvrles in the potetatial well. Tlae bond-nuunberdistribut.ion in the regiouu confined by a pair of' salute taaolectrles is responsible for the conaaplicated change of the solttte-solute distribution ftrtactior'x by tlae soltrte-solvent infer;xction ?rt tlaedistant region. It is SIIOXVII that the change of' the bond uatrrnber xvith tlue soJtzte-soltzte distanceis expressed by tlae soltrte-soltrte distribtrtion ['trractions witlu tlae slaifts in distance by tlae widtlaof the potential xvell at zero solttte-solvent interactiora.
- 社団法人日本物理学会の論文
- 1999-06-15
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