Cooperative Chemical Kinetics

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概要

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• Kikuchi's theory of irreversible cooperative phenomena is extended so as to treat cooperative chemical kinetics. A state distinguished chemically from others (a chemical state) is made up of a number of physically distinguishable states. When probabilities of transitions between states belonging to a same chemical state are large compared with those between states belonging to different chemical states, the path entropy of a heat bath is shown to be S_b(t, t + Δt) = Const. -ΔF_s(t, t + Δt)/2T, where ΔF_s(t, t + Δt) is the amount of free energy increase in the system during the time interval Δt, and T is the temperature of the heat bath. This expression of the path entropy of a heat bath can be used in chemical kinetics, since statistical weight parameters of a chemical system are given in a form exp(-βf), f's are not energies but free energies.

• 社団法人日本物理学会の論文
• 1967-02-05

著者

• Go Nobuhiro

  Department Of Physics Faculty Of Science Kyoshu University

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