Aggregation of Polyelctrolytes in Solutions

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概要

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• In this paper, in the first place the characteristic distribution of counterions around the assembly of many polyions is investigated on the basis of the exact solution of the general two-dimentional Poisson-Boltzmann equation, and from this result the interaction between two rod-like polyions is also derived. Through these theoretical studies, it is found that counterions interact cooperatively with polyions and strongly depress the repulsive force between two polyions. In the second place, the mechanism of the precipitation of polyions with salts is studied by various experimental methods. It is emphasized here that the specific ion-binding and hydration have the essential effects on the precipitation phenomenon of polyions.

• 理論物理学刊行会の論文
• 1961-00-00

著者

• Imai Nobuhisa

  Department Of Physics Faculty Of Science Nagoya University

関連論文

• Interaction between Rod-like Polyelectrolytes
• An Integral Representation of the Poisson-Boltzmann Equation
• Aggregation of Polyelctrolytes in Solutions
• The Theory of the Additivity Rule and the Interaction in Rod-Like Polyelectrolyte Solutions

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