Structures of Some Copper (II) Complexes Containing S_2 O_6^2^- Ion Part II. : The Structures of [Cu (S_2 O_6) (H_2 O) (terp)]_∞ and [Cu (S_2 O_6) (H_2 O)_2 (bpy) ]_∞

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概要

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• The crystal structures of two rare copper (II) complexes with the coordinated dithionate ion (S2O6-) [Cu (S2O6) (H2O) (terp)]∞ [1], [Cu (S2O6) (H2O)2 (bpy)]∞ [2] have been determined using the X-ray diffraction technique. (terp : 2,2',2''-terpyridyl, bpy : 2,2'-bipyridine(1)) The crystal of [1] is morioclinic with space group P21/m (No.11)(2) and [2] is monocIinic with P2/a (No.13)(2). The geometry around the Cu atom is a distorted octahedron for [1] and [2]. In both structures, the S2O62- ion coordinates as a bidentate ligand through O atoms and links the two Cu atoms to form infinite chains. The bond distances of Cu-O (S2O62- ion) are 2.320 (4) Å in [1] and 2.434 (4), 2.489 (4) Å in [2], respectively.

• 山形大学の論文
• 2001-02-15

著者

• Ishii Minoru

  Chemistry Laboratory Faculty Of Education Yamagata University

関連論文

• Structures of Some Copper (II) Complexes Containing S_2 O_6^2^- Ion Part I. : The Structures of [Cu (H_2 O)_3 (phen) ] S_2 O_6 ・H_2 O and [Cu(S_2 O_6) (phen)_2 ]
• Structures of Some Copper (II) Complexes Containing S_2 O_6^2^- Ion Part II. : The Structures of [Cu (S_2 O_6) (H_2 O) (terp)]_∞ and [Cu (S_2 O_6) (H_2 O)_2 (bpy) ]_∞

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