臭素酸塩電解製造に関する基礎的研究(II) : 臭素酸塩の生成速度
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The kinetics of the decomposition of hypobromite solutions were investigated in a limited range of pH and initial concentrations by measuring the change of concentration of both hypobromite and bromite. The results can be satisfactorily explained on the basis of two second-order consecutive reactions, the first involving the formation of bromite, and the second a comparatively fast reaction between bromite and hyporomite. In the pH range considered, the assumption that the reactions take place exclusively between an undissociated acid molecule and an anion does not give satisfactory agreement with experiment. The better agreement is obtained by assuming reactions involving either free bromine or two uncharged molecules of acid.
- 岡山理科大学の論文
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- 臭素酸塩電解製造に関する基礎的研究(II) : 臭素酸塩の生成速度
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