金属錯塩中におけるアルキレン鎖長に依存した対カチオンの結合様式の類似性
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概要
- 論文の詳細を見る
The crystals of [NiII(dmit)2]−(dmit=1,3-dithiole-2-thione-4,5-dithiolate) salts with three kinds of counter di-cations (1,1-Cn-di-3-X-pyridinium (CndX) ; Cn alkylene chain length ; n=4, 6, 8, 10 and X functional groups ; COOCH3, COCH3, COC6H5), were prepared. The effects of both weak hydrogen bond and alkylene chain length have been investigated by X-ray crystallographic analysis. dX cations formed one-dimensional structure linked by C-H…O hydrogen bonds. The type of linkage depended on the alkylene chain length. Cations with short (n=4) and long (n=10) chains were linked by C-H…O hydrogen bond with dimer type. For those of medium (n=6, 8), however, the cations adopted linear type.
- 日本結晶学会の論文
- 2010-10-31
著者
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Tomono Kazuaki
Department Of Chemistry Faculty Of Science Tokyo University Of Science
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友野 和哲
山口大学大学院理工学研究科
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Tomono Kazuaki
Department Of Material Chemistry Graduate School Of Science And Engineering Yamaguchi University
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